Natalia was engaged to Antonio Alcol and they also promised to get married and be each other loving spouse. But this promise was never fulfilled as she called off her engagement just before a day she was about to get married. There is no any information related to her love affairs, boyfriend and divorce.
Fascinating environment of Spain impressed her and she also desired to offer them something. Her real talent was singing and music and then in the early morning of 2000 she decided to form a pop rock band. She got collaborated with Ángel Reyero and Pablo Domínguez and together they formed a Spanish pop/rock band La 5ª Estación. Within a year they released their debut album, Primera Toma. It was released on 3rd of December 2001. They also began recording their second album under the title Flores de Alquiler and it was finally released on 22nd of June 2004. She is also a solo artist and her debut solo album, Natalia Jimenez was finally released on 21st of June 2011. She has been earning lucrative amount of salary and her net worth is said to be around $10 million.