On 26th of August 1962, Maury got married to Phyllis Minkoff. As a married couple, they remained together for more than one and half decade and they also became parents of two sweet children during this married life. They got divorced in 1979.
When Maury was in WTTN, he met love of his life Connie Chung. There he used to serve as an anchorman and Connie worked there as a secretary. They first met in 1969. After he dissolved his first married life, he began dating her and they finally got married on 2nd of December 1984.
Maury received his primary education from Landon School. He was also able to complete his high school graduation from there in 1957 and then he joined University of Pennsylvania. There he majored in television journalism and finally earned his undergraduate degree in 1962. Soon after his graduation, he joined WWDC as a reporter. He also did publicity there. In 1966, he joined WTTG-TV as a news reporter and sportscaster and then in 1967, he became the co host of the talk show, Panorama. He began hosting the show, The Maury Povich Show since 1991 and for this role he earned the salary of $7,000,000 per year. His net worth is said to be around $45 million.