In 2010, Ali was seen with Roberto Martinez having romantic love affairs with him. She met him when she was on The Bachelorette. They got engaged in 2010; however, this engagement was dissolved at the end of 2011.
In 2013, Ali began her love affairs with Kevin Manno. Kevin Manno is a television and radio host from United States. At the end of 2015, they announced their engagement. On 6th of January 2016, they revealed that they were expecting their first child together.
At a young age, Ali got enrolled at Mount Greylock Regional High School. She completed her high school graduation from there in 2002 and then she joined Clark University with a major in Psychology. She earned her Bachelor of Arts from there in 2006. She has been active in TV shows since 2010. On 4th of January 2010, she appeared on ABC's reality show The Bachelor series. She appeared in this show as one of its cast members. She quit this show within short period of time but was back after being engaged to Roberto Martinez. She began her broadcasting career from local Fox news station. There she worked as a weekly morning show correspondent. She joined E! News in August 2013. Her net worth is said to be around $600 thousand dollars.