In 2004, Ali was found having romantic love affairs with Kevin Sacre. Kevin Sacre is an actor from United Kingdom. He is mainly famous for his role in soap opera show, Hollyoaks. They called off their love life in 2006.
Few months later after Ali broke up with Kevin, she was found with Nick Kennedy. Nick is a former rugby union player. He has also played in 2006 Churchill Cup. She dated him as her boyfriend but this love life lasted till 2009.
In 2009, Ali was seen dating Brian Fortuna. Brian Fortuna is a professional ballroom dancer. He is also known for being an instructor. However, this love life was also short lived. In 2013, she got engaged to Tom Clay but this engagement was also called off within short period of time. She has not been married and divorced.
In 1992, Ali joined Redroofs Theatre School. She studied there for the next three years and then she joined Claires Court School, The College. When she was 10, she made her acting debut by appearing in the TV series, Jane Eyre. In 1997, she starred the role of Fairy in FairyTale: A True Story. She got her rise in fame after she began appearing in the Channel 4 soap opera Hollyoaks. The actual figure about her net worth is unknown.